Metrology for Substrate Back Side Contamination

Application Note RSMD010

Contamination elements

MRAM elements: Lower limits of detection (LLD) [atoms/cm²]

  Mg Al Fe Co Mn Ta Ru Pt
TXRF-V310 6e8 9e8 1e7 1e7 1e7 1e8 ? ?
TXRF 310Fab 6e10 9e10 1e9 1e9 1.4e9 1.3e10 1e10 8e9

After etching of MTJ layer and cap layer, those elements cause contamination on the backside of the silicon substrate.

RSMD010 Figure 1

BAC-TXRF

Backside contamination must be measured to avoid cross-contamination of the product line.

BAC-TXRF is a suitable technique for the MRAM application.

RSMD010 Figure 2Diffusion length of Cu at various temperatures for 1 hr.

About BAC-TXRF

RSMD010 Figure 3Frontside and backside handling with flipping robot arm

Contamination from the tunnel layer material (MgO)

RSMD010 Figure 4

The W-M excitation source is suitable to measure light-element contamination, such as Na, Mg, and Al.

Contamination from the free and pinned layer material (CoFeB)

RSMD010 Figure 5 Free and Pinned

Contamination from the Pt and Ru layers

RSMD010 Figure 5

Other detected elements

RSMD010 Figure 6 Other elements detected

Results after cleaning

RSMD010 Figure 7 Results after cleaning

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