OIL-MULTI-PAK

Pre-calibration package for multi-element analysis of oils using 

OIL-MULTI-PAK is an application package for multi-element oil analysis that removes the usual XRF roadblocks: the costly, time-consuming need to build calibrations with suitable reference materials, the corrections required for variable C/H/O matrices and film-induced attenuation, the geometry effects from X-ray optics, and the trial-and-error of choosing sample films. By supplying pre-built standard intensities, optimized analytical parameters, and drift-correction samples, it delivers fast, accurate quantification across a wide range of oils, from used lubricants and base-oil variants to fuels such as heavy oil, diesel, and gasoline.

OIL-MULTI-PAK

OIL-MULTI-PAK Overview

Built specifically for the ZSX Primus IVi, OIL-MULTI-PAK comes pre-calibrated to quantify 27 elements across the concentration ranges encountered in fuels and lubricants, with sulfur covered from trace levels up to about 4.5 mass%. The data media installed through ZSX Guidance loads sensitivity coefficients derived from 120 mineral-oil standards, optimized measurement conditions, and the FP-based correction models. Startup is straightforward: install, run the included drift-correction, confirm against the supplied validation oil, and you’re analyzing. Default conditions measure all targets in roughly 17 minutes, and the package’s reference LLDs (for example, ~1 ppm for S and ~0.4 ppm for Fe under the default timings) are suitable for routine QC as well as R&D.

The corrections aren’t hand-waving; they’re implemented in ways that remove common failure modes. Hydrocarbon/oxygen variation is corrected using Rh Kα Compton scattering treated as an integrated peak, which stabilizes the matrix estimate across different fill volumes and even in the presence of Mo, where Mo Kβ overlap is explicitly deconvolved. Film effects are handled by a new model that bakes film material, thickness, and impurity into the theoretical intensity—so you can choose polyester or polypropylene to suit the chemistry without rebuilding calibrations. Geometry effects from deep-origin fluorescence in light matrices are corrected in the FP calculation, so you don’t have to hold sample mass constant; when needed, sample thickness is computed from mass and density rather than eyeballing the meniscus.

The package is practical out of the box. Beyond the software, it ships with drift-correction samples, blank paraffin, a multi-element validation oil, disposable cells and syringes, two film types, a density cup, and a portable scale—everything you need to get reliable numbers without hunting for consumables. You can also spin light-weight, task-specific apps from the master package (e.g., sulfur-only methods for fuels) to increase throughput. Accuracy has been demonstrated against JPI heavy-oil standards and NIST SRMs for diesel and gasoline, and repeatability on a commercial lubricant shows sub-1% RSD for elements between ~100–2000 ppm, consistent with routine plant-floor precision.

OIL-MULTI-PAK Features

Using a unique algorithm based on scattered X-rays, the system automatically corrects for variations in hydrocarbon (CH₂) and oxygen (O) composition.
This ensures stable and accurate X-ray fluorescence (XRF) analysis regardless of the type of oil sample, including fuel oils and lubricants.
Film material, thickness, and impurity information are incorporated into the theoretical intensity calculation, enabling consistent sensitivity constants across different films.
The film correction function improves flexibility in film selection and enhances analytical reproducibility.
Geometric effects caused by variations in liquid sample thickness are corrected through theoretical modeling.
This minimizes analytical errors related to sample volume differences and allows precise quantification down to the ppm level.
The system supports simultaneous measurement of up to 27 elements, including Na, Mg, Al, Si, P, and S, covering a wide concentration range from ppm to several mass percent.
It can be applied to various types of oil and fuel samples such as heavy oil, light oil, and gasoline.
Film presets in ZSX Guidance help you select commercially available films appropriate to the oil type
Typical total measurement time is about 17 minutes for all 27 elements; background angles are shared where possible to cut time.
Complete accessory kit: data media, drift-correction samples, blank paraffin, validation oil, 10 mL density cup, portable scale, cells, disposable syringes, two film types, and a liquid-cell assembly tool.

OIL-MULTI-PAK Specifications

Element Conc. range (ppm) Element Conc. range (ppm)
Na (9)–5000 Co (0.4)–600
Mg (2.5)–4000 Ni (0.4)–600
Al (1.6)–1250 Cu (0.4)–1250
Si (1.8)–2000 Zn (0.4)–5000
P (0.9)–5000 Br (0.3)–2000
S (1.0)–4.5 mass% Mo (1.5)–2000
Cl (4.6)–2.0 mass% Ag (3.3)–500
K (1.0)–2000 Cd (3.3)–500
Ca (0.8)–3.0 mass% Sn (3.3)–600
Ti (1.0)–600 Sb (3.3)–600
V (1.0)–600 Ba (2.9)–8000
Cr (0.7)–600 Pb (1.0) 1250
Mn (0.7)–600 Bi (1.0) 600
Fe (0.4)–2000

The values of lower limit of detection (LLD) are indicated in parentheses. The LLD depends on the measurement time, the sample film, and the composition of the analysis sample.

OIL-MULTI-PAK Resources

Rigaku Journal article

OIL-MULTI-PAK for multi-element analysis of oils using pre-calibration package Read the Article

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