Peak-to-background Ratio and X-ray Count Standard Deviation

About the calculator

The calculator calculates peak-to-background (P/B) ratio and standard deviation of X-ray count with a P/B ration in consideration.

How to use it

  1. Enter the total X-ray intensity at the peak position in [counts] unit.
  2. Enter the background level in [counts] unit.

Theory

Variables

Symbol Meaning Units
T Total X-ray counts counts
P Peak only X-ray counts counts
B Background level counts
P/BM Peak-to-background ratio
σT/T Relative standard deviation based on total X-ray counts
σ/T Relative peak standard deviation with background consideration counts
Graph showing signal and background intensity versus scan axis with a zoomed section illustrating repeated measurements at position X and statistical variation of σ and 3σ.

The peak-to-background ratio is defined as P/B. The peak intensity is calculated as P = T – B.

The relative standard deviations based on total X-ray count is determined as:

\(\frac{\sigma_T}{T} = \frac{1}{\sqrt{T}}, \text{ where } \sigma_T = \sqrt{T}.\)

The relative standard deviations with background consideration is determined as:

\(\frac{\sigma}{T} = \frac{\sqrt{T + B}}{P}.\)

Intensity Parameters
[counts]
[counts]
Signal Intensity
8988
[counts]
Total intensity - Background intensity
Peak to Background Ratio
3.6
Standard Deviation and Relative Standard Deviation
Total Intensity Statistics
107
[counts]
Standard deviation (total) = √(Total intensity)
0.9%
[%]
Relative standard deviation (total)
Peak Intensity Statistics
118
[counts]
Standard deviation (peak only) = √(Total + Background)
1.3%
[%]
Relative standard deviation (peak)
Summary
Signal Intensity
8988 counts
Peak/Background Ratio
3.6
Total RSD
0.9%
Peak RSD
1.3%