Titanium on Steel
Scope
The measurement of titanium (Ti) conversion coating on galvanized steel is demonstrated.
Background
Aluminum and steel are often coated with a protective conversion coating, also called passivate or passivation coating, to prevent oxidation and corrosion of the base metal. Conversion coatings include chromium (Cr), titanium (Ti), vanadium (V), manganese (Mn), nickel (Ni), phosphorus (P), or zirconium (Zr). A phosphate coating may also be applied to minimize wear on cutting tools and stamping machines.
Aluminum is often coated for use in aircraft parts, aluminum window frames, and other similar industries where the aluminum is exposed to weathering. Steel for
the automotive industry is typically first galvanized with a zinc coating before the conversion coating is applied. Protected steel is also used for outdoor sheds and other similar uses where steel is exposed to weathering. Conversion coating also helps in the retention of paint for the final finished product.
Model: NEX QC
Calibration
An empirical calibration was built using a set of standards assayed by careful weigh-strip-weigh.
Element: Ti Units: mg/ft² |
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Sample I.D. | Standard value | Calculated value |
STD 1 | 0.83 | 0.835 |
STD 2 | 1.90 | 1.905 |
STD 3 | 3.50 | 3.643 |
STD 4 | 4.64 | 4.472 |
STD 5 | 7.29 | 7.254 |
STD 6 | 10.82 | 10.883 |
STD 7 | 17.43 | 17.418 |
Correlation plot Ti on galvanized steel
Recovery and repeatability
To demonstrate repeatability (precision), the low and high calibration standards were chosen. Each sample was measured in a static position for ten repeat analyses with typical results shown below.
Element: Ti Units: mg/ft² |
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Sample I.D. | Standard value | Average value | Std. dev | % Relative |
STD 1 | 0.83 | 0.845 | 0.024 | 2.9 |
STD 7 | 17.43 | 17.440 | 0.069 | 0.4 |
Conclusion
The performance shown here demonstrates NEX QC+ provides excellent sensitivity and performance for the measurement of titanium conversion coatings on galvanized steel.
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