Titanium on Aluminum

Application Note EDXRF1619

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Scope

The measurement of titanium (Ti) conversion coating on aluminum is demonstrated.

Background

Aluminum and steel are often coated with a protective conversion coating, also called passivate or passivation coating, to prevent oxidation and corrosion of the base metal. Conversion coatings include chromium (Cr), titanium (Ti), vanadium (V), manganese (Mn), nickel (Ni), phosphorus (P) or zirconium (Zr). A phosphate coating may also be applied to minimize wear on cutting tools and stamping machines.

Aluminum is often coated for use in aircraft parts, aluminum window frames, and other similar industries where the aluminum is exposed to weathering. Steel for the automotive industry is typically first galvanized with a zinc coating before the conversion coating is applied. Protected steel is also used for outdoor sheds and other similar uses where steel is exposed to weathering. Conversion coating also helps in the retention of paint for the final finished product.

NEX QC+ high-resolution EDXRF analyzerModel: NEX QC+

Calibration

An empirical calibration was built using a set of standards assayed by careful weigh-strip-weigh. 

Element: Ti
Units: mg/ft²
Sample I.D. Standard value Calculated value
STD 1 0.06 0.046
STD 2 0.24 0.196
STD 3 0.53 0.603
STD 4 1.16 1.177
STD 5 2.57 2.521
STD 6 4.10 4.117

EDXRF1619 Correlation plot Ti on aluminumCorrelation plot Ti on aluminum

Recovery and repeatability

To demonstrate repeatability (precision), the three calibration standards were chosen. Each sample was measured in a static position for ten repeat analyses with typical results shown below.

Element: Ti
Units: mg/ft²
Sample I.D. Standard value Average value Std. dev % Relative
STD 2 0.24 0.214 0.009 3.8
STD 4 1.16 1.173 0.009 0.8
STD 6 4.10 4.136 0.017 0.4

Conclusion

The performance shown here demonstrates NEX QC+ provides excellent sensitivity and performance for the measurement of titanium conversion coatings on aluminum.

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