Iron Oxide in Silica Sand

    Application Note EDXRF1177

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    Scope

    The analysis of iron oxide in silica sand is demonstrated.

    Background

    One of the major uses of silica sand is to make glass, and in particular, glass bottles. The iron content is one of the major factors that affect the color of the glass. Low iron sands are used to produce clear glass for bottles, while sand with higher iron content is used to make amber glass bottles. Thus, both at the quarry site and in the manufacturing process, monitoring the iron content is very important to ensure the quality of the glass products. The Rigaku NEX QC is an ideal tool for reliably measuring the iron content in sand, and can be used at the quarry along the production line to help ensure the highest quality while minimizing wastes and cost overruns.

    800x610 NEX QC+ (S in Crude screen)_picture_2020.06.25Model: NEX QC

    Calibration

    Seven assayed standards were used for calibration. 

    Element: Fe₂O₃
    Units: %
    Sample I.D. Standard value Calculated value
    A 0.0151 0.0152
    B 0.0315 0.0319
    C 0.0332 0.0328
    D 0.0400 0.0410
    E 0.0495 0.0491
    F 0.0683 0.0682
    G 0.1210 0.1210

    EDXRF1177 Correlation plot Fe2O3

    Correlation plot Fe₂O₃

    Repeatability

    To demonstrate repeatability (precision), the low and high calibration standards were each measured without moving the sample between measurements.

    Element: Fe₂O₃
    Units: %

    I.D.

    Standard value

    NEX QC average result

    Std. dev (σ)

    A

    0.0151

    0.0153

    0.0008

    G

    0.1210

    0.1201

    0.0008

    Conclusion

    The results show NEX QC provides excellent performance for the measurement of iron oxide in silica sand. The NEX QC offers a simple and fast means of analysis during the QA/QC process in the production of glass bottles, as well as for screening at the quarry.

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