Metals & Alloys

    Application Note EDXRF1595

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    Scope

    The semi-quantitative measurement of metals in various alloys is demonstrated using the Fundamental Parameters approach without the need for a reference library.

    Background

    Standard and specialty alloys vary in metal composition to give the alloy its specific physical, mechanical, and chemical properties. Analyzing alloy composition by XRF (X-ray Fluorescence) is important to ensure the proper alloy grade meets the needs for its specific use. The Rigaku NEX QC+ QuantEZ system gives the operator a quick, simple, and reliable means of checking alloy composition without damaging or changing the sample.

    NEX QC+ QuantEZ workstationModel: NEX QC+ Quant-EZ

    Results

    Sample: SS 303
    Units: mass %
    Element Specification range NEX QC+ QuantEZ result Statistical error
    Fe Balance 68.8
    Cr 17.0 – 19.0 19.3 0.025
    Ni 8.0 – 10.0 7.35 0.014
    Mn 2.0 max 1.88 0.010
    Si 1.0 max 0.64 0.003

    Sample: SS 304
    Units: mass %
    Element Specification range NEX QC+ QuantEZ result Statistical error
    Fe Balance 69.4
    Cr 18.0 – 20.0 20.0 0.024
    Ni 8.0 – 10.5 7.9 0.014
    Mn 2.0 max 1.00 0.009
    Si 1.0 max 0.69 0.003

    Sample: Al 7075
    Units: mass %
    Element Specification range NEX QC+ QuantEZ result Statistical error
    Al 87.1 – 91.4 92.4
    Cr 0.18 – 0.28 0.24 0.002
    Cu 1.2 – 2.0 1.18 0.002
    Fe 0.5 max 0.27 0.002
    Mg 2.1 – 2.9 ND*
    Mn 0.3 max 0.03 0.001
    Si 0.4 max ND*
    Ti 0.2 max 0.06 0.002
    Zn 5.1 – 6.1 5.34 0.003

    *Mg and Si at low levels are not detectable in an aluminum alloy due to aluminum absorption of Mg and Si X-rays


    Sample: MONEL Alloy K-500
    Units: mass %
    Element Specification range NEX QC+ QuantEZresult Statistical error
    Ni 63.0 min 64.2
    Mn 1.5 max 0.84 0.006
    Fe 2.0 max 0.01 0.002
    Si 0.5 max 0.09 0.002
    Cu 27.0 – 33.0 31.2 0.024
    Al 2.30 – 3.15 2.77 0.012
    Ti 0.35 – 0.85 0.60 0.009

    Sample: Hastelloy B-3
    Units: mass %
    Element Specification range NEX QC+ QuantEZ result Statistical error
    Ni 65.0 min 64.9
    Cr 1.0 – 3.0 1.83 0.016
    Mo 27.0 – 32.0 27.8 0.017
    Mn 1.0 max 0.67 0.009
    Cu 0.2 max 0.50 0.010
    Si 0.1 max 0.43 0.006
    Ti 0.2 max ND*
    Co 3.0 max ND*
    V 0.2 max ND*
    Fe 1.0 – 3.0 1.64 0.009

    *Trace levels of Ti and V and low levels of Co are not detectable in this alloy due to high levels of Ni and Mo that absorb transition metal X-rays

    Sample: Alloy R405
    Units: mass %
    Element Certified value NEX QC+ QuantEZ result Statistical error
    Cu 32.3 32.2 0.025
    Ni 64.8 64.9
    Al 0.08 ND*
    Fe 1.31 1.37 0.005
    Mn 1.03 1.14 0.006
    Si 0.05 ND*
    Ti 0.005 ND*
    Cr 0.008 ND*

    *Trace levels of Al, Si, Ti, and Cr are not detectable in this alloy due to high levels of Cu and Ni that absorb transition metal and light element X-rays


    Sample: CDA 544 Units: mass %
    Element Certified value NEX QC+ QuantEZ result Statistical error
    Cu 87.7 88.9
    Fe 0.02 ND*
    Pb 3.87 2.82 0.011
    Ni 0.077 ND*
    Sn 4.73 3.97 0.006
    Zn 3.55 3.67 0.009

    *Trace levels of Fe and Ni are not detectable in this alloy due to high levels of Cu that absorb transition metal X-rays

    Conclusion

    The NEX QC+ QuantEZ provides a rapid, non- destructive means for semi- quantitative measurement for screening, identification and other semi-quant needs without the need for a special library. To optimize the FP results for a specific family of alloys, the QuantEZ software also gives the user a simple way of creating a Matching Library using one more certified alloy sample of that family type, providing a fast and simple means to design libraries to fit exact analysis needs.

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